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  • Titre : Lecture_15_EFM-MFM.pdf
  • Submitted by : Anonymous
  • Description : o EFM measures electric field gradient distribution above the sample surface, through ... nanoparticles, i.e. formation of surface charges in surface layers. Electroncis based on lateral assembly of nanocrystals Mol. Syst. Des. Eng., 2017, 2, pp440.

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Anyone likes to do proposal and presentation individually?

First and middle names

Group #

Last name

CHAVEZ

MCCUTCHEN

KENNEDY

PARKER

KRIEGER

SERBINOWSKI

BURTON

MAHMOOD

YAO

HONG

BASKARAN

THOMPSON

JOSE JACOB

JARED STEVEN

ASHLEY MARIE

MITCHELL DENNIS

ISAAC

KONRAD

RACHEL M

TAWSIF

YUE

JINHWAN

KARTHIKEYAN

BENJAMIN CLYDE

1

1

1

2

2

2

3

3

3

4

4

4

Lecture 15: Two special modes for AFM: Electrostatic Force Microscopy (EFM)
and Magnetic Force Microscopy (MFM)

• basic principles and mechanisms of EFM and MFM;

• two scanning modes;

• typical applications: with EFM for applications in interfacial charge

transfer and separation, and MFM for exploring the nanostructural

magnetic information’s (real case studies as inspired from mother

Nature).

EFM also called:
scanning electrostatic potential microscopy (SEPM)
(Force àfeedback; potential àmeasurement)

or Kelvin probe force microscopy (KPFM)

What is EFM?

o

o

o

o

EFM is a secondary imaging mode derived from AFM.

EFM measures electric field gradient distribution above the sample surface, through

measuring local electrostatic interaction between a conductive tip and a sample .

In EFM, a voltage is applied between the tip and the sample.

The bias is used to create and modulate an electrostatic field between the tip and the

substrate.

o

The cantilever(cid:1)s resonance frequency and phase change with the strength of the electric field

gradient and are used to construct the EFM image.

o

EFM can be used to distinguish conductive and insulating regions in a sample.

What are other secondary imaging modes derived from AFM?

Electrostatic Force Microscopy (EFM)

Electrostatic Interaction Upon Voltage Application

100 µm

25 µm

3 µm

20 nm

bias = 1 V

Tip apex

Cantilever

Tip cone

Cantilever frequency change due to electrostatic interaction

Phase Imaging

Two types of EFM measurement:

1. Lifted mode: constant height
l Because the electrostatic forces interact at greater distances than van der

Waals forces, so electrical force information can be separated from
surface topography simply by increseasing the tip-to-sample distance —
lift up the tip.

l Dual scanning — Grounded tip (no bias) first acquires surface topography

in the tapping mode, then the tip is lifted up (typically 5-50 nm), and
retraces the surface profile maintaining constant tip-surface separation.

l A constant voltage is maintained on the tip. As the tip moves over an

attractive electric field gradient, it is pulled toward the sample. When the
tip traverses a repulsive gradient, it is pushed away from the sample.
l The deflection (or frequency change) of the cantilever, proportional to the
charge density, can be measured using the standard light-lever system.

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