Anyone likes to do proposal and presentation individually?
First and middle names
Group #
Last name
CHAVEZ
MCCUTCHEN
KENNEDY
PARKER
KRIEGER
SERBINOWSKI
BURTON
MAHMOOD
YAO
HONG
BASKARAN
THOMPSON
JOSE JACOB
JARED STEVEN
ASHLEY MARIE
MITCHELL DENNIS
ISAAC
KONRAD
RACHEL M
TAWSIF
YUE
JINHWAN
KARTHIKEYAN
BENJAMIN CLYDE
1
1
1
2
2
2
3
3
3
4
4
4
Lecture 15: Two special modes for AFM: Electrostatic Force Microscopy (EFM)
and Magnetic Force Microscopy (MFM)
• basic principles and mechanisms of EFM and MFM;
• two scanning modes;
• typical applications: with EFM for applications in interfacial charge
transfer and separation, and MFM for exploring the nanostructural
magnetic information’s (real case studies as inspired from mother
Nature).
EFM also called:
scanning electrostatic potential microscopy (SEPM)
(Force àfeedback; potential àmeasurement)
or Kelvin probe force microscopy (KPFM)
What is EFM?
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EFM is a secondary imaging mode derived from AFM.
EFM measures electric field gradient distribution above the sample surface, through
measuring local electrostatic interaction between a conductive tip and a sample .
In EFM, a voltage is applied between the tip and the sample.
The bias is used to create and modulate an electrostatic field between the tip and the
substrate.
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The cantilever(cid:1)s resonance frequency and phase change with the strength of the electric field
gradient and are used to construct the EFM image.
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EFM can be used to distinguish conductive and insulating regions in a sample.
What are other secondary imaging modes derived from AFM?
Electrostatic Force Microscopy (EFM)
Electrostatic Interaction Upon Voltage Application
100 µm
25 µm
3 µm
20 nm
bias = 1 V
Tip apex
Cantilever
Tip cone
Cantilever frequency change due to electrostatic interaction
Phase Imaging
Two types of EFM measurement:
1. Lifted mode: constant height
l Because the electrostatic forces interact at greater distances than van der
Waals forces, so electrical force information can be separated from
surface topography simply by increseasing the tip-to-sample distance —
lift up the tip.
l Dual scanning — Grounded tip (no bias) first acquires surface topography
in the tapping mode, then the tip is lifted up (typically 5-50 nm), and
retraces the surface profile maintaining constant tip-surface separation.
l A constant voltage is maintained on the tip. As the tip moves over an
attractive electric field gradient, it is pulled toward the sample. When the
tip traverses a repulsive gradient, it is pushed away from the sample.
l The deflection (or frequency change) of the cantilever, proportional to the
charge density, can be measured using the standard light-lever system.